BigBallBellyGirl:
When I regained weight, I put on over 400 pounds in 3.5 years through stuffing multiple times a week, eating 10 to 25,000 calories a day even when not stuffing, and a steady diet of bread, cheese, pasta, pizza, potatoes, and fast food. I was just over 600 lb when I had going to the hospital with a cardiac emergency, but I had vitamin deficits of vitamin B, C, potassium, and magnesium. It's definitely very possible to have a massive calories surplus and a vitamin deficit.
I get into a shocking number of arguements with people in and out of the community about malnutrition in obese people. They conflate being fat with starving.
If you got fat while not eating a balanced diet or not taking a multi-vitamin, the missing nutrients are not going to magically spawn into you. You still have to comsume them.